During the 26th National Congress (2011) she was elected general secretary.
Rovira won a seat in the Parliament of Catalonia during the elections of 2012 and in 2015 stood in the elections to the Parliament of Catalonia with the pro-independence coalition Together for Yes.Between 2008 and 2012 Rovira was general secretary of the European Free Alliance.
Rovira was the representative-secretary of the Young Lawyers Association of Catalonia (2006–2007), manager of the Group of Young Lawyers of Vic (2004–2006) who she represented in the Governing Board of the Vic Law Association, member of the Platforma Solidà ria de la UPF (1999), and representative of the students association Jurists without borders (1997–1999).
She is also a member of the Sagals of Osona.
On 22 December 2017 she was imputed for sedition after the Catalan declaration of independence.
On 23 March 2018, Rovira left Spain to avoid attending a Supreme Court summons, stating that she had chosen the "path to exile".