Having learnt the printing trade in Victoria, he came to Western Australia in 1896, living for periods in Kalgoorlie, Perth, and Fremantle.
Mann eventually moved to Busselton, where in 1903 he established what would become the town's main newspaper, the South-Western News.
He would remain the proprietor and editor of the publication until 1935.
He was also involved with various press organisations, serving as the president of the Australian Provincial Press Association (a forerunner of the Australian Press Council) from 1923 to 1925 and also as an Australian delegate to the Empire Press Union.
Standing for the Nationalist Party, Mann was elected to parliament at the 1926 Legislative Council elections, defeating the sitting Country Party member, Francis Willmott.
He was re-elected in 1932, 1938, and 1946, switching to the newly formed Liberal Party in 1945.