Through her father she was great-granddaughter of Prince Stanislaw Lubomirski and through her mother she was granddaughter of Prince Józef Klemens Czartoryski.
She had two sisters: Dorota and Jadwiga Julia (she married Eugène, 8th Prince of Ligne) and brother Jerzy Henryk.
On 6 July 1829, in Przeworsk she married Prince Wladyslaw Hieronim Sanguszko.
They had five children:
Jadwiga Klementyna Sanguszko (1830–1918) – she married Prince Adam Stanislaw Sapieha
Roman Damian Sanguszko (1832–1917) – he married Countess Karolina of Thun and Hohenstein, great-granddaughter of Count Alois Friedrich von Brühl
Pawel Roman Sanguszko (1834–1876) – he married firstly Countess Marie Gfn von der Borch-Warkland and secondly Georgina Apponyi de Nagy-Appony
Helena Sanguszko (1836–1891)
Eustachy Stanislaw Sanguszko (1842–1903) – he married Countess Konstancja Anna ZamoyskaShe died in 1868.